A psychiatrist is given care of Rhoda Miller (real name "AF 709"), a life-like, sophisticated, but naïve android that eventually learns how human society works and begins showing -- or at least emulating -- rudimentary emotions.
Day Zero
12 Parsecs
He-Man and the Masters of the Universe
Knight Watchmen
Neon Genesis Evangelion
AI Romantic
X-Bomber
Fantastic Man
Spider-Man and His Amazing Friends
My Adventures with Superman
Justice League
Super Force